Home > information > News > 2020 > 【Paper】Blue Perovskite Nanocrystal Light‐Emitting Devices via the Ligand Exchange with Adamantane Diamine Takayuki Chiba*, Shota Ishikawa, Jun Sato, Yoshihito Takahashi, Hinako Ebe, Satoru Ohisa, Junji Kido*

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May 12, 2020 【Paper】Blue Perovskite Nanocrystal Light‐Emitting Devices via the Ligand Exchange with Adamantane Diamine Takayuki Chiba*, Shota Ishikawa, Jun Sato, Yoshihito Takahashi, Hinako Ebe, Satoru Ohisa, Junji Kido*

Blue Perovskite Nanocrystal Light‐Emitting Devices via the Ligand Exchange with Adamantane Diamine

Takayuki Chiba*, Shota Ishikawa, Jun Sato, Yoshihito Takahashi, Hinako Ebe, Satoru Ohisa, Junji Kido*

https://onlinelibrary.wiley.com/doi/10.1002/adom.202000289

Abstract
Metal halide perovskite nanocrystals (NCs) have been established as promising materials for light‐emitting devices (LEDs) due to their interesting optoelectrical properties, including high photoluminescence quantum yield (PLQY) and high color purity with narrow full width at half maximum (FWHM). However, blue perovskite LEDs, with an emission wavelength below 470 nm, require further investigation to improve their performance. Here, it is demonstrated that mixed‐halide CsPb(Cl/Br)3 NCs prepared by ligand exchange with the rigid bidentate structure of adamantane‐1,3‐diamine (ADDA) can be used for blue LEDs. The ligand exchange of CsPb(Cl/Br)3 NCs with ADDA improves PLQY without changing the peak wavelength and FWHM. The LEDs based on ligand exchange NCs with ADDA show an external quantum efficiency (EQE) of 0.49%. Moreover, a quaternary ammonium salt, oleylammonium chloride (OAM‐Cl), is also investigated as an interfacial layer to reduce current density. The LED fabricated with OAM‐Cl reaches an EQE of 1.1% and luminance of 43.2 cd m−2 at the electroluminescence wavelength of 456 nm, representing significantly higher performance compared to that of LEDs without OAM‐Cl layers. Therefore, the ligand exchange of NCs with ADDA and the use of a passivation layer comprising OAM‐Cl facilitate an improvement in the LED performance.

📚 Kido/Sasabe/Chiba Lab HP >> https://oled.yz.yamagata-u.ac.jp/view.cgi?p=376

2020 List of News

Dec. 28, 2020
 Paper 
A paper related to Ayato ARAI (M2) and Associate Professor Hisahiro SASABE (Kido/Sasabe/Chiba Lab) titled "π-Extended carbazole derivatives as host materials for highly efficient and long-life green phosphorescent OLEDs" was published on Chemistry A European Journal (IF: 4.857) (Wiely).
Dec. 17, 2020
 Paper 
A paper related to Daiki SAITO (M2) and Associate Professor Hisahiro SASABE (Kido/Sasabe/Chiba Lab) titled "Improved operational lifetime of deep-red phosphorescent organic light-emitting diodes using a benzothienobenzothiophene (BTBT)-based p-type host material" was published on Journal of Materials Chemistry C (IF: 7.059).
Dec. 14, 2020
 Paper 
A paper related to Kohei NAKAO (D3) and Associate Professor Hisahiro SASABE (Kido/Sasabe/Chiba Lab) titled "Novel Series of Mononuclear Aluminum Complexes for High-Performance Solution-Processed Organic Light-Emitting Devices" was published on Angewandte Chemie International Edition (IF: 12.959). This is a cooperative research with Katagiri Laboratory.
Dec. 10, 2020
 Paper 
A paper related to Tomohiro MARUYAMA (M2) and Associate Professor Hisahiro SASABE (Kido/Sasabe/Chiba Lab) titled "Dibenzothiophene/terpyridine conjugated asymmetric electron transporters for high-efficiency and long-life green phosphorescent OLEDs" was published on Chemistry Letters (IF: 1.625).
Nov. 30, 2020
 News Release 
(Yamagata) The news related to professor Junji KIDO titled "Yamagata University gave a lecture to the middle school students on science and handmade the OLED" was released.
Nov. 21, 2020
 News Release 
(Yamagata) The news related to Smart MIRAI House titled "The students from Jinmachi Primary School (Higashine city) experienced future life with OLED for a school trip" was released.
Nov. 20, 2020
 TV Broadcast 
A school trip to Smart MIRAI House from Jinmachi Primary School (Higashine city) was showed on TV (YTS Gojidasu) on November, 20.
Nov. 20, 2020
 Paper 
A paper related to Jun SATO who graduated in 2019 and Assistant Professor Takayuki CHIBA (Kido/Sasabe/Chiba Lab) titled "Neodymium Chloride-Doped Perovskite Nanocrystals for Efficient Blue Light-Emitting Devices" was published on ACS Applied Materials & Interfaces (IF: 8.758).
Nov. 19, 2020
 Information 
The students from Jinmachi Primary School (Higashine city) visited Smart Mirai House for a school trip.
Nov. 05, 2020
 News Release 
(Nikkei) The news related to Associate Professor Kuniaki NAGAMINE titled "Yamagata University starts to form a R&D site for a research using sweat to detect the component instead of blood collecting" was released.
Nov. 02, 2020
 Information 
A research result related to seat sensor developed by Tokito/Kumaki/Sekine lab 's research group was displayed at the lobby (1st floor) of Yamagata City Hall.
Nov. 02, 2020
 Adopted 
A research subject of assistant professor Tomohito SEKINE (research representative) was adopted by a research grand of ATI (Foundation Advanced Technology Institute).
Nov. 02, 2020
 Adopted 
A research subject of assistant professor Tomohito SEKINE (research representative) was adopted by A-STEP Tryout, a research support program of Japan Science and Technology Agency (JST).
Nov. 02, 2020
 Award 
Assistant Professor Tomohito SEKINE (Tokito/Kumaki/Sekine Lab) received the 9th New Chemical Technology Encouraging Award from Japan Association for Chemical Innovation (JACI).
Nov. 02, 2020
 Paper 
A paper related to Assistant Professor Tomohito SEKINE and Mai ABE (M1) titled "Microporous Induced Fully Printed Pressure Sensor for Wearable Soft Robotics Machine Interfaces" was published on Advanced Intelligent Systems.
Nov. 02, 2020
 Paper 
A paper related to Reo MIURA (M1) and Assistant Professor Tomohito SEKINE titled "Printed Soft Sensor with Passivation Layers for the Detection of Object Slippage by a Robotic Gripper" was published on Micromachines.
Nov. 02, 2020
 Information 
Professor Shizuo TOKITO will give a report on the research achievements in (SIP) Smart Logistics Service Symposium 2020 (Vision Center Nagatacho, Tokyo) on November 6.
Nov. 02, 2020
 Lecture 
Professor Shizuo TOKITO will be invited as a guest speaker in 6th International Conference on Nanoscience and Nanotechnology (ICONN-2021), which will be held online on February 1st ~ 3rd, 2021.
Oct. 30, 2020
 News Release 
(Nikkei Web) The news related to Associate Professor Kuniaki NAGAMINE titled "Yamagata University starts to form a R&D site for a research using sweat to detect the component instead of blood collecting" was released.
Oct. 29, 2020
 Web Release 
Innovation Center for Organic Electronics (INOEL) participated in JFlex2021 on-line exhibition and shows its research results.
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